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Multiscale modeling of endohedral fullerenes. Molecular dynamics, electronic structure, and molecular properties

Project goals

The proposal addresses current problems of endohedral fullerene science using multiscale computational approaches. We put stress on understanding the molecular properties, dynamics, and chemical bonding in endohedral fullerenes. Endohedral fullerenes arepromising in materials science, medicine, memory devices, fuell cells, supraconductors, etc. We intend to model endohedral fullerenes and their molecular properties with inclusion of all the relevant physical effects, such as electron correlation, relativity, dynamics as well as media effects in the calculations. This will be done by combination of the electronic structure theory methods with the simulation approaches in a multiscale fashion. Our aim is to provide answers to current hot questions in the field of endohedral fullerenes via computational modelling to gain new understanding and stimulate new experiment. Using the freshly built magnetic circular dichroism device in our laboratory, we intend to perform novel MCD experiments for endohedral fullerenes to obtain more detailed picture about their electronic structure. Experimental results will be interpreted using theoretical calculations.

Keywords

endohedrální fullerenyvćeúrovňové modelyspektroskopické vlastnostielektronová strukturamagne

Public support

  • Provider

    Czech Science Foundation

  • Programme

    Standard projects

  • Call for proposals

    Standardní projekty 12 (SGA02009GA-ST)

  • Main participants

  • Contest type

    VS - Public tender

  • Contract ID

    203/09/2037

Alternative language

  • Project name in Czech

    Víceúrovňové modelování endohedrálních fullerenů. Dynamika, elektronová struktura a spektroskopické vlastnosti

  • Annotation in Czech

    Řešení problematiky endohedrálních fullerenů pomocí teoretických metod se zaměřením na spektroskopické vlastnosti, dynamiku a elektronovou strukturu endohedrálních fullerenů. Víceúrovňové modelování se zahrnutím odpovídajících fyzikálních efektů, jako dynamika, relativistické efekty a vliv okolí.

Scientific branches

  • R&D category

    ZV - Basic research

  • CEP classification - main branch

    CF - Physical chemistry and theoretical chemistry

  • CEP - secondary branch

  • CEP - another secondary branch

  • 10403 - Physical chemistry

Completed project evaluation

  • Provider evaluation

    U - Uspěl podle zadání (s publikovanými či patentovanými výsledky atd.)

  • Project results evaluation

    The project gone according to plan both in terms of expertise and in terms of disbursement of funds.

Solution timeline

  • Realization period - beginning

    Jan 1, 2009

  • Realization period - end

    Dec 31, 2011

  • Project status

    U - Finished project

  • Latest support payment

    Apr 16, 2011

Data delivery to CEP

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

  • Data delivery code

    CEP12-GA0-GA-U/02:2

  • Data delivery date

    May 2, 2016

Finance

  • Total approved costs

    3,179 thou. CZK

  • Public financial support

    3,179 thou. CZK

  • Other public sources

    0 thou. CZK

  • Non public and foreign sources

    0 thou. CZK

Basic information

Recognised costs

3 179 CZK thou.

Public support

3 179 CZK thou.

100%


Provider

Czech Science Foundation

CEP

CF - Physical chemistry and theoretical chemistry

Solution period

01. 01. 2009 - 31. 12. 2011