Highly Fluorescent Stereochemical Hybrides
Public support
Provider
Czech Science Foundation
Programme
Standard projects
Call for proposals
SGA0202600001
Main participants
Univerzita Karlova / Přírodovědecká fakulta
Contest type
VS - Public tender
Contract ID
26-23391S
Alternative language
Project name in Czech
Highly Fluorescent Stereochemical Hybrides
Annotation in Czech
The main objective of the proposed project is a design and syntheses of new hitherto unknown chiral stereochemical hybrids (PCP-Hel hybrides) possessing elements of planar and helical chirality exemplified by the [2.2]paracyclophane (PCP) and [n]helicene scaffolds (Hel). It is presumed that a combination of two stereochemical elements and the presence of specific functionalities will lead to new class substances with enhanced photophysical properties such as high photoluminescence (PL) and high luminescence dissymmetry factor (LDF) that will eventually have high CPL brightness. A high PL will be ensured by incorporation of substituted azonia moiety, azabora, or azaplatinacycles into the basic framework. Emission in the red-light region will be targeted. Regarding the LDF, it is presumed that a combination of a rigid chiral [2.2]paracyclophane unit and a [n]helical scaffold will result in its increase. The essential part of the project is evaluation of products' configurational and thermal stability, UV/vis and NIR absorption, photoluminescence, CPL properties, etc.
Scientific branches
R&D category
ZV - Basic research
OECD FORD - main branch
10401 - Organic chemistry
OECD FORD - secondary branch
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OECD FORD - another secondary branch
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CEP - equivalent branches <br>(according to the <a href="http://www.vyzkum.cz/storage/att/E6EF7938F0E854BAE520AC119FB22E8D/Prevodnik_oboru_Frascati.pdf">converter</a>)
CC - Organic chemistry
Solution timeline
Realization period - beginning
Jan 1, 2026
Realization period - end
Dec 31, 2028
Project status
Z - Beginning multi-year project
Latest support payment
—
Data delivery to CEP
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data delivery code
CEP26-GA0-GA-R
Data delivery date
Apr 29, 2026
Finance
Total approved costs
9,045 thou. CZK
Public financial support
9,045 thou. CZK
Other public sources
0 thou. CZK
Non public and foreign sources
0 thou. CZK