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Structural basis for function within the family of nitric oxide synthases

Project goals

The family of nitric oxide synthases (inducible-iNOS; endothelial-eNOS; neuronal-nNOS) combines the unique properties of heme- and flavin-containing proteins in one polypeptide chain to achieve the, production of a small, diffusible, reactive biologicalmessenger and cytotoxic agent, nitric oxide (NO). NO functions in cell-to-cell signaling and plays a critical role in numerous physiological processes. The aberrant production of NO is responsible for a number of pathologies. The crystal structures of eNOS, iNOS, and nNOS heme domain and that of FAD/NADPH domain of nNOS have been solved. NOS is an important drug target and the structural details of holoenzyme are essential for this. However, a complete structure is unavailable either for the reductasedomain or the holoenzyme. To accomplish this goal we will utilize mammalian and prokaryotic expression systems to overexpress (i) all three NOS isoforms and (ii) its naturally occurring variants (muscle specific variant, ĽNOS, iNOS bronchial epithelium

Keywords

nitric oxidenitric oxide synthasesprotein structure

Public support

  • Provider

    Czech Science Foundation

  • Programme

    Standard projects

  • Call for proposals

    Standardní projekty 8 (SGA02005GA-ST)

  • Main participants

  • Contest type

    VS - Public tender

  • Contract ID

    303/05/0336

Alternative language

  • Project name in Czech

    Strukturální základy funkce rodiny syntáz oxidu dusnatého

  • Annotation in Czech

    Syntázy oxidu dusnatého (tři savčí isoformy: indukovatelna forma-iNOS; endotelová-eNOS; neuronální-nNOS) jsou neobvyklé hemoflavoproteiny. Výsledkem jejich enzymatické aktivity je tvorba oxidu dusnatého (NO). Tato malá, difuzibilní a reaktivní molekula hraje důležitou roli v mezibuněčné signalizaci a účastní se řady klíčových fyziologických pochodů. Vychýlená produkce NO hraje důležitou roli v patogeneze aterosklerózy, septického šoku, nádorových onemocnění, neurodegenerace a dalších chorobných stavů. Na ovlivnění aktivity NOS je proto zaměřena řada farmakologických intervencí. Poznání kompletní struktury NOS je důležitým předpokladem cíleného farmakologického zásahu. Byly určeny krystalové struktury hemových domén iNOS, eNOS, nNOS a větší části reduktázové domény nNOS. Přes mnohaleté úsilí nebyla popsána struktura kompletní NOS ani její kompletní reduktázová doména. Chceme pomocí savčích a prokaryotických expresních systémů připravit (i) všechny izoformy NOS a (ii) jejich vybrané varianty [nNOS

Scientific branches

  • R&D category

    ZV - Basic research

  • CEP classification - main branch

    CE - Biochemistry

  • CEP - secondary branch

    EB - Genetics and molecular biology

  • CEP - another secondary branch

    EI - Biotechnology and bionics

  • 10603 - Genetics and heredity (medical genetics to be 3)
    10604 - Reproductive biology (medical aspects to be 3)
    10605 - Developmental biology
    10608 - Biochemistry and molecular biology
    10609 - Biochemical research methods
    20801 - Environmental biotechnology
    20802 - Bioremediation, diagnostic biotechnologies (DNA chips and biosensing devices) in environmental management
    20803 - Environmental biotechnology related ethics
    20901 - Industrial biotechnology
    20902 - Bioprocessing technologies (industrial processes relying on biological agents to drive the process) biocatalysis, fermentation
    20903 - Bioproducts (products that are manufactured using biological material as feedstock) biomaterials, bioplastics, biofuels, bioderived bulk and fine chemicals, bio-derived novel materials
    30101 - Human genetics
    30401 - Health-related biotechnology
    30402 - Technologies involving the manipulation of cells, tissues, organs or the whole organism (assisted reproduction)
    30403 - Technologies involving identifying the functioning of DNA, proteins and enzymes and how they influence the onset of disease and maintenance of well-being (gene-based diagnostics and therapeutic interventions [pharmacogenomics, gene-based therapeutics])
    30404 - Biomaterials (as related to medical implants, devices, sensors)
    30405 - Medical biotechnology related ethics
    40401 - Agricultural biotechnology and food biotechnology
    40402 - GM technology (crops and livestock), livestock cloning, marker assisted selection, diagnostics (DNA chips and biosensing devices for the early/accurate detection of diseases) biomass feedstock production technologies, biopharming
    40403 - Agricultural biotechnology related ethics

Completed project evaluation

  • Provider evaluation

    V - Vynikající výsledky projektu (s mezinárodním významem atd.)

  • Project results evaluation

    The family of nitric oxide synthases (NOS) combines together into one protein the unique properties of hemoproteins and flavoproteins. The result of their enzymatic, immensely complex controlled action is the generation of a small, rapidly diffusing bior

Solution timeline

  • Realization period - beginning

    Jan 1, 2005

  • Realization period - end

    Dec 31, 2007

  • Project status

    U - Finished project

  • Latest support payment

    May 2, 2007

Data delivery to CEP

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

  • Data delivery code

    CEP08-GA0-GA-U/04:3

  • Data delivery date

    Dec 16, 2008

Finance

  • Total approved costs

    3,201 thou. CZK

  • Public financial support

    3,201 thou. CZK

  • Other public sources

    0 thou. CZK

  • Non public and foreign sources

    0 thou. CZK