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Raman spectroscopic study of the uranyl carbonate mineral zellerite

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00023272%3A_____%2F08%3A%230000997" target="_blank" >RIV/00023272:_____/08:#0000997 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Raman spectroscopic study of the uranyl carbonate mineral zellerite

  • Original language description

    Raman and infrared spectra of the uranyl mineral zellerite, Ca[(UO2)(CO3)2(H2O)2] 3H2O, were measured and tentatively interpreted. U-O bond in uranyl and O-H center dot center dot center dot O hydrogen bonds were calculated from the vibrational spectra.The presence of structurally nonequivalent water molecules in the crystal structure of zellerite was inferred. A proposed chemical formula of zellerite is supported. Raman bands at 3514, 3375 and 2945 cm-1 and broad infrared bands at 3513, 3396 and 3326cm-1 are related to the v OH stretching vibrations of hydrogen-bonded water molecules. Observed wavenumbers of these vibrations prove that in fact hydrogen bonds participate in the crystal structure of zellerite. The presence of two bands at 1618 and 1681 cm-1 proves structurally distinct and nonequivalent water molecules in the crystal structure of zellerite.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    DB - Geology and mineralogy

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Raman Spectroscopy

  • ISSN

    0377-0486

  • e-ISSN

  • Volume of the periodical

    39

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    5

  • Pages from-to

  • UT code for WoS article

    000256167200005

  • EID of the result in the Scopus database