A Raman spectroscopic study of the different vanadate groups in solid-state compounds - model case: mineral phases vesignieite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2 .2H2O]
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00023272%3A_____%2F11%3A%230001562" target="_blank" >RIV/00023272:_____/11:#0001562 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/jrs.2906" target="_blank" >http://dx.doi.org/10.1002/jrs.2906</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/jrs.2906" target="_blank" >10.1002/jrs.2906</a>
Alternative languages
Result language
angličtina
Original language name
A Raman spectroscopic study of the different vanadate groups in solid-state compounds - model case: mineral phases vesignieite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2 .2H2O]
Original language description
Raman spectroscopy has been used to study vanadates in the solid state. The molecular structure of the vanadate minerals vesignieite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2. 2H2O] have been studied by Raman spectroscopy and infrared spectroscopy. The spectra are related to the structure of the two minerals. The Raman spectrum of vesignieite is characterized by two intense bands at 821 and 856 cm-1 assigned to nu1 (VO4)3- symmetric stretching modes. A series of infrared bands at 755, 787 and 899cm-1 are assigned to the nu3 (VO4)3- antisymmetric stretching vibrational mode. Raman bands at 307 and 332 cm-1 and at 466 and 511 cm-1 are assigned to the nu2 and nu4 (VO4)3- bending modes. The Raman spectrum of volborthite is characterized by the strong band at 888 cm-1, assigned to the nu1 (VO3) symmetric stretching vibrations. Raman bands at 858 and 749 cm-1 are assigned to the nu3 (VO3) antisymmetric stretching vibrations; those at 814 cm-1 to the nu3 (VOV) antisymmetric vibrations
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
DB - Geology and mineralogy
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Raman Spectroscopy
ISSN
0377-0486
e-ISSN
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Volume of the periodical
42
Issue of the periodical within the volume
8
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
1701-1710
UT code for WoS article
000294767700015
EID of the result in the Scopus database
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