Raman spectroscopy of hydrogen arsenate group (AsO3OH)2- in solid state compounds: cobalt-cotaining zinc arsenate mineral, koritnigite (Zn,Co)(AsO3OH) .H2O
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00023272%3A_____%2F11%3A%230001568" target="_blank" >RIV/00023272:_____/11:#0001568 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/jrs.2690" target="_blank" >http://dx.doi.org/10.1002/jrs.2690</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/jrs.2690" target="_blank" >10.1002/jrs.2690</a>
Alternative languages
Result language
angličtina
Original language name
Raman spectroscopy of hydrogen arsenate group (AsO3OH)2- in solid state compounds: cobalt-cotaining zinc arsenate mineral, koritnigite (Zn,Co)(AsO3OH) .H2O
Original language description
Raman spectra of two well-defined types of koritnigite crystals from the Jachymov ore district, Czech Republic, were recorded and interpreted. No substantial differences were observed between both crystal types. The observed Raman bands were attributed to the (AsO3OH)2- stretching and bending vibrations as well as stretching and bending vibrations of water molecules and hydroxyl ions. The non-interpreted Raman spectra of koritnigite from the RRUFF database and the published infrared spectra of cobaltkoritnigite were used for comparison. The O-H...O hydrogen bond lengths in the crystal structure of koritnigite were inferred from the Raman spectra and compared with those derived from the X-ray single-crystal refinement. The presence of (AsO3OH)2- units in the crystal structure of koritnigite was proved from the Raman spectra, which supports the conclusions of the X-ray structure analysis.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
DB - Geology and mineralogy
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Raman Spectroscopy
ISSN
0377-0486
e-ISSN
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Volume of the periodical
42
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
534-539
UT code for WoS article
000288544000042
EID of the result in the Scopus database
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