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The new K, Pb-bearing uranyl-oxide mineral kroupaite: Crystal-chemical implications for the structures of uranyl-oxide hydroxy-hydrates

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00023272%3A_____%2F20%3A10135102" target="_blank" >RIV/00023272:_____/20:10135102 - isvavai.cz</a>

  • Alternative codes found

    RIV/68378271:_____/20:00537722 RIV/00216224:14310/20:00116943

  • Result on the web

    <a href="https://pubs.geoscienceworld.org/msa/ammin/article-abstract/105/4/561/583348/The-new-K-Pb-bearing-uranyl-oxide-mineral?redirectedFrom=fulltext" target="_blank" >https://pubs.geoscienceworld.org/msa/ammin/article-abstract/105/4/561/583348/The-new-K-Pb-bearing-uranyl-oxide-mineral?redirectedFrom=fulltext</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.2138/am-2020-7311" target="_blank" >10.2138/am-2020-7311</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    The new K, Pb-bearing uranyl-oxide mineral kroupaite: Crystal-chemical implications for the structures of uranyl-oxide hydroxy-hydrates

  • Original language description

    Kroupaite (IMA 2017-031), ideally KPb0.5[(UO2)8O4(OH)10].10H2O, is a new uranyl-oxide hydroxylhydrate mineral found underground in the Svornost mine, Jachymov, Czechia. Electron-probe micro-analysis (WDS) provided the empirical formula (K1.28Na0.07)1.35(Pb0.23Cu0.14Ca0.05Bi0.03Co0.02Al0.01)0.48[(UO2)7.90(SO4)0.04O4.04(OH)10.00].10H2O, on the basis of 40 O atoms apfu. Sheets in the crystal structure of kroupaite adopt the fourmarierite anion topology, and therefore kroupaite belongs to the schoepite-family of minerals with related structures differing in the interlayer composition and arrangement, and charge of the sheets. Uptake of dangerous radionuclides (Sr-90 or Cs-135) into the structure of kroupaite and other uranyl-oxide hydroxy-hydrate is evaluated based on crystal-chemical considerations and Voronoi-Dirichlet polyhedra measures. These calculations show the importance of these phases for the safe disposal of nuclear waste.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10504 - Mineralogy

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    American Mineralogist

  • ISSN

    0003-004X

  • e-ISSN

  • Volume of the periodical

    105

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    561-568

  • UT code for WoS article

    000523599300011

  • EID of the result in the Scopus database