The metal-rich part of the Co-Ni-P system at 800 oC
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00025798%3A_____%2F06%3A00000226" target="_blank" >RIV/00025798:_____/06:00000226 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The metal-rich part of the Co-Ni-P system at 800 oC
Original language description
The metal-rich portion of the Co-Ni-P system was studied experimentally at 800 oC by means of evacuated silica glass tube technique. Five binary phases: Co2P, Ni2P, Ni12P5, Ni5P2, Ni3P and five ternary phosphides solid solutions: (Co1-x, Nix)3P, ?1-(Ni1-xCox)2P (hexagonal), ?2-Co1-xNix)2P (orthorhombic),(Co1-x,Nix)12P5 and (Co1-x,Nix)5P2 were found to be stable in the system. Cobalt has a significant influence on the structure of (Ni,Co)2P solid solutions and, therefore, cobalt contents might change thecrystal structure of naturally occurring phosphides with the Ni/P = 2:1 ratio. Ni-rich, cobalt-containing phosphides with the Ni/P ratio = 3:1 and 2:1, isotypic with minerals schreibersite and barringerite, could possibly be found in meteorites. Likewise, phosphides with Ni/P ratio = 12:5 and 5:2 may possibly be found, but in close association with natural Ni-rich phosphides.
Czech name
Kovem bohatá část soustavy Co-Ni-P při 800 oC.
Czech description
Fázové vztahy v kovy bohaté části soustavy Co-Ni-P byly studovány v zatavených, evakuovaných kamenných trubicích. V soustavě bylo identifikováno pět binárních fází: Co2P, Ni2P, Ni12P5, Ni5P2, Ni3P a pět ternárních pevných roztoku: (Co1-x, Nix)3P, ë1-(Ni1?xCox)2P (hexagonální), ë2-Co1?xNix)2P (ortorombický),(Co1-x,Nix)12P5 a (Co1-x,Nix)5P2. Kobalt má významný vliv na strukturu Ni-Co fosfidu.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
DB - Geology and mineralogy
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA205%2F05%2F0459" target="_blank" >GA205/05/0459: The system Os-Mo-S and its geological application</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2006
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Europ. Journ. of Mineralogy
ISSN
0935-1221
e-ISSN
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Volume of the periodical
5
Issue of the periodical within the volume
18
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
545-550
UT code for WoS article
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EID of the result in the Scopus database
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