A novel sorbent for chromatographic separations: A silica matrix modified with non-covalently bonded tetrakis(-cyclodextrin)-porphyrin conjugates
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11110%2F13%3A10190636" target="_blank" >RIV/00216208:11110/13:10190636 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/13:43895057
Result on the web
<a href="http://dx.doi.org/10.1002/jssc.201300116" target="_blank" >http://dx.doi.org/10.1002/jssc.201300116</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/jssc.201300116" target="_blank" >10.1002/jssc.201300116</a>
Alternative languages
Result language
angličtina
Original language name
A novel sorbent for chromatographic separations: A silica matrix modified with non-covalently bonded tetrakis(-cyclodextrin)-porphyrin conjugates
Original language description
We prepared new phases for LC that consisted of silica modified with non-covalently bonded tetrakis(-cyclodextrin)-porphyrin (where cyclodextrin is CD) conjugates. The effects of the porphyrin core, type of spacer and -CD moieties on the behaviours of the modified phases for the separation of aromatic compounds (benzene, toluene, ethylbenzene, propylbenzene, butylbenzene, pentylbenzene, o-terphenyl, triphenylene, phenol and caffeine) and fluorinated aromatic compounds (pentafluorobenzonitrile, pentafluoronitrobenzene and hexafluorobenzene) were studied using the Tanaka test. The results indicate that the non-covalent substitution of silica with CD-based macromolecules that have a porphyrin core can be a very effective method for preparing novel sorbents with specific chromatographic properties for applications in LC.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CE - Biochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP206%2F12%2F0453" target="_blank" >GAP206/12/0453: Affinity capillary electromigration methods for selective nanoanalysis of biomolecules and investigation of their interactions</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Separation Science
ISSN
1615-9306
e-ISSN
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Volume of the periodical
36
Issue of the periodical within the volume
13
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
2072-2080
UT code for WoS article
000322567300003
EID of the result in the Scopus database
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