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Quantification of ethosuximide in human serum by GC-MS after butyl chloroformate derivatization

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11110%2F16%3A10336907" target="_blank" >RIV/00216208:11110/16:10336907 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/16:10336907

  • Result on the web

    <a href="http://web.natur.cuni.cz/analchem/isc/isc12.pdf" target="_blank" >http://web.natur.cuni.cz/analchem/isc/isc12.pdf</a>

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Quantification of ethosuximide in human serum by GC-MS after butyl chloroformate derivatization

  • Original language description

    A simple, sensitive and robust method for determination of anti-epileptic drug ethosuximide in human serum using GC-MS was developed and validated for clinical toxicology purposes. This method employs an emerging class of derivatization agents: alkyl chloro-formates allowing the efficient and rapid derivatization of both the amino and carboxylic groups of the tested antiepileptic drug within seconds. The derivatization protocol was optimized using the Design of Experiment, and the entire sample preparation requires less than 5 minutes. Linear calibration curves were obtained in the concentration range 0.5-150 mu g/mL, with adequate accuracy (98.0-109.0%) and precision (< 10.4%). The method was successfully applied to quantification of ethosuximide in the serum of patients in both therapeutic and toxic concentration ranges

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CB - Analytical chemistry, separation

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    PROCEEDINGS OF THE 12TH INTERNATIONAL STUDENTS CONFERENCE MODERN ANALYTICAL CHEMISTRY

  • ISBN

    978-80-7444-044-1

  • ISSN

  • e-ISSN

  • Number of pages

    6

  • Pages from-to

    17-22

  • Publisher name

    CHARLES UNIV, FAC SCIENCE

  • Place of publication

    PRAGUE 2

  • Event location

    Prague

  • Event date

    Sep 22, 2016

  • Type of event by nationality

    EUR - Evropská akce

  • UT code for WoS article

    000391253800004