Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11160%2F14%3A10292854" target="_blank" >RIV/00216208:11160/14:10292854 - isvavai.cz</a>
Result on the web
<a href="http://eurekaselect.com/121702" target="_blank" >http://eurekaselect.com/121702</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.2174/2213346101666140421220156" target="_blank" >10.2174/2213346101666140421220156</a>

Result language
angličtina
Original language name
Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal
Original language description
This work demonstrates that low antimicrobial toxicity C2-substituted imidazolium-based ILs, with either ester or amide groups in the side chain, can successfully replace harmful volatile organic compounds (VOCs) in the asymmetric carbonyl-ene reaction of phenylglyoxal with four alkenes catalysed by {[(R)-BINAP]Pd}(SbF6)2. Furthermore, the Pd(II) catalyst immobilised in these ILs was recycled and reused up to 5 times without loss of enantioselectivity, although a decrease in yield was observed.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F10%2F2048" target="_blank" >GAP207/10/2048: Chiral Quinazoline Alkaloids: Potential Prototypes of Novel Antiasthmatics and Organocatalysts</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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