Consequences of isosteric replacement of benzene for pyrazine in phthalocyanines
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11160%2F22%3A10458592" target="_blank" >RIV/00216208:11160/22:10458592 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=PxqO~GzPhD" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=PxqO~GzPhD</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1142/S1088424622300038" target="_blank" >10.1142/S1088424622300038</a>
Alternative languages
Result language
angličtina
Original language name
Consequences of isosteric replacement of benzene for pyrazine in phthalocyanines
Original language description
Tetrapyrazinoporphyrazines (TPyzPzs) likely represent the most investigated group of azaanalogs of phthalocyanines. This review highlights the author's contributions in this field and summarizes the most important features of these interesting macrocycles with the aim of emphasizing the differences from the parent phthalocyanines. In particular, uniqueness in synthesis, spectral, photophysical and electrochemical properties are discussed. Thanks to systematic investigation of intramolecular charge transfer with TPyzPzs as electron acceptors, detailed structure-activity relationships of this ultrafast quenching process have been disclosed. This opened the door for the use of TPyzPzs as fluorescence sensors and quenchers in oligodeoxynucleotide probes, the latter being unique for TPyzPzs, which have not been investigated with phthalocyanines. These two applications seem to be much more suitable for TPyzPzs than photodynamic therapy, where the phthalocyanines typically have superior in vitro activities.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
30104 - Pharmacology and pharmacy
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Porphyrins and Phthalocyanines
ISSN
1088-4246
e-ISSN
1099-1409
Volume of the periodical
26
Issue of the periodical within the volume
12
Country of publishing house
FR - FRANCE
Number of pages
18
Pages from-to
765-782
UT code for WoS article
000849625600001
EID of the result in the Scopus database
2-s2.0-85137406261