Unusual cis/trans isomerism in octahedral nickel(II) complexes with 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) as a ligand
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F01%3A00107046" target="_blank" >RIV/00216208:11310/01:00107046 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Unusual cis/trans isomerism in octahedral nickel(II) complexes with 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) as a ligand
Original language description
Nickel(II) ion reacts with 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) (H4L1) at room temperature with formation of cis-[Ni(L1)]2- complex. The complex was crystallised in several forms in dependence on conditions of isolation (temperature, pH, solvent mixture). Crystal structures of cis-O,O-[Ni(H2L1)] (1), cis-O,O-[Ni(H2L1)] 2H2O (2), cis-O,O-[Ni(H3L1)]Cl H2O (3) and cis-O,O-[Ni(H4L1)]Cl2 2H2O (4) were determined by X-ray diffraction.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F99%2FM037" target="_blank" >GA203/99/M037: Centre of molecular and crystal structures</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Collection of Czechoslovak Chemical Communications
ISSN
0010-0765
e-ISSN
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Volume of the periodical
66
Issue of the periodical within the volume
2
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
9
Pages from-to
363-381
UT code for WoS article
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EID of the result in the Scopus database
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