Localization and Coordination of Mg2+ Cations in Ferrierite: Combined FTIR Spectroscopic and Computation Investigation of CO Adsorption Complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F09%3A10000079" target="_blank" >RIV/00216208:11310/09:10000079 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/09:00331253
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Localization and Coordination of Mg2+ Cations in Ferrierite: Combined FTIR Spectroscopic and Computation Investigation of CO Adsorption Complexes
Original language description
Experimental data were interpreted based on a very good agreement between theoretical and experimental results. The most intense band in the spectra centered at 2205 cm-1 was assigned to monocarbonyl complexes formed on Mg2+ cations located in the six-member ring separating two adjacent FER cages (P6 site); it is concluded that Mg2+ cations exchange preferably into this site. An unusually high site-specificity of ?CO observed for CO complexes formed in Mg-FER can be exploited in the investigation of preferable exchange sites of Mg2+ in zeolites and in the investigation of the localization of Al pairs in zeolites.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2009
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of physical chemistry c
ISSN
1932-7447
e-ISSN
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Volume of the periodical
113
Issue of the periodical within the volume
25
Country of publishing house
GB - UNITED KINGDOM
Number of pages
11
Pages from-to
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UT code for WoS article
000267205700032
EID of the result in the Scopus database
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