Unusual Intramolecular Bridging Reaction in Thiacalix[4]arene Series

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F09%3A10000822" target="_blank" >RIV/00216208:11310/09:10000822 - isvavai.cz</a>

Alternative codes found

RIV/60461373:22310/09:00022820

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Unusual Intramolecular Bridging Reaction in Thiacalix[4]arene Series

Original language description

Thiacalix[4]arene immobilized in the cone conformation undergoes a direct formylation reaction giving unusual products in high yields. The Duff reaction (urotropine/TFA) leads to unprecedented intra-molecularly bridged compounds possessing two formyl groups on the opposite para- or para-/meta- positions. The comparison with the corresponding classical calix[4]arene analogues indicates an amazingly different reactivity of the thiacalix[4]arene system.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Organic Letters

ISSN

1523-7060

e-ISSN

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Volume of the periodical

11

Issue of the periodical within the volume

18

Country of publishing house

US - UNITED STATES

Number of pages

4

Pages from-to

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UT code for WoS article

000269670700041

EID of the result in the Scopus database

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