C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F09%3A10001105" target="_blank" >RIV/00216208:11310/09:10001105 - isvavai.cz</a>

Alternative codes found

RIV/00216275:25310/09:00008659

Result on the web

—

DOI - Digital Object Identifier

—

Result language

angličtina

Original language name

C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides

Original language description

Triorganotin(IV) hydrides and cyclopentadienides as well as hexaorganodistannanes containing the moiety L-CN (2-(N,N-dimethylaminomethyl)phenyl-) as chelating ligand and phenyl, n-butyl or t-butyl substituents were prepared and characterized by NMR and XRD. The compounds reveal trigonal bipyramidal geometry around the central tin atom except for the distannanes in which the tin atom has tetrahedral configuration. The di-n-butyl distannane cannot be oxidized by oxygen or heavier chalcogens and give no tin radical when irradiated by UV light or treated with the TEMPO - free radical at room temperature. L-CN(t-Bu)(2)SnH undergoes reaction in solution toward the corresponding distannane. The hydrostannation reaction of L-CN(n-Bu)(2)SnH with ferrocenylacetylene was investigated. The CO2 activation by L-CN(n-Bu)(2)SnH was also examined.

Czech name

—

Czech description

—

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

—

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

—

Volume of the periodical

694

Issue of the periodical within the volume

18

Country of publishing house

CH - SWITZERLAND

Number of pages

7

Pages from-to

—

UT code for WoS article

000268265200020

EID of the result in the Scopus database

—