Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F09%3A10001113" target="_blank" >RIV/00216208:11310/09:10001113 - isvavai.cz</a>

Alternative codes found

RIV/00216275:25310/09:00008301

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives

Original language description

The reactions of a C,N-chelated ((L-CN)(2)M, where L-CN is 2-((dimethylamino)methyl)phenyl and M is Sn (1) or Pb (2)) stannylene and plumbylene with di-n-butylbis(eta(5)-cyclopentadienyl)zirconium (3) were studied. In the case of the stannylene, the trinuclear carbene-like complex [(L-CN)(2)Sn](2)CP2Zr (4) was isolated as the major product. The second product isolated resultedfirom transmetalation of the CN-chelating ligand from tin to zirconium, followed by 1-butene coupling to the coordinated aryne (C,N-chelating ligand) (5). In the lead case, the major product was the complex 5. Byproducts were elemental lead, thefiree ligand ((LH)-H-CN), butane, and 1-butene. The oxidation of 4 by oxygen gave the six- trioxatrizircona cyclic complex (6) and an eight-membered tetraoxa tetrastanna cyclic complex (7).

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Organometallics

ISSN

0276-7333

e-ISSN

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Volume of the periodical

28

Issue of the periodical within the volume

10

Country of publishing house

US - UNITED STATES

Number of pages

4

Pages from-to

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UT code for WoS article

000266156900023

EID of the result in the Scopus database

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