Hydrogenation of phenylacetylene and 3-phenylpropyne using Rh(diene) complexes under homogeneous and heterogeneous conditions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F10%3A10001453" target="_blank" >RIV/00216208:11310/10:10001453 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/10:00022981
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Hydrogenation of phenylacetylene and 3-phenylpropyne using Rh(diene) complexes under homogeneous and heterogeneous conditions
Original language description
Hydrogenation of phenylacetylene (PA) and 3-phenylpropyne (PP) was carried out using [Rh(diene)Cl](2) complexes (diene is hexadiene (HD), cycloocta-1,5-diene (COD), norborna-2,5-diene (NBD)) in their immobilized forms and compared with hydrogenation in homogeneous arrangement. Immobilization brings significant increase of the catalytic activity and product selectivity in the step-wise hydrogenation to corresponding vinyl-resp. allyl-benzenes. Diene-ligand effect was apparent in PA hydrogenation: the product selectivity decreased in order Rh(HD) } Rh(NBD) } Rh(COD) and catalytic activity decreased in order Rh(HD) } Rh(COD) } Rh(NBD).
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Applied Catalysis A: General
ISSN
0926-860X
e-ISSN
—
Volume of the periodical
372
Issue of the periodical within the volume
1
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
6
Pages from-to
—
UT code for WoS article
000273933800005
EID of the result in the Scopus database
—