SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F10%3A10001455" target="_blank" >RIV/00216208:11310/10:10001455 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/10:00341739
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization
Original language description
New hybrid catalysts for olefin metathesis were prepared by immobilization of Hoveyda-Grubbs type Ru alkylidenes on a siliceous SBA-15 support via exchange of chloro ligands for substituted carboxylates. Catalysts proved a high activity in ring closing metathesis of 1,7-octadiene and diethyl diallylmalonate, reusability and low Ru leaching. In Ring Opening Metathesis Polymerization of norbornene and cyclooctene, SBA-15 supported catalyst gave higher yields of high-molecular-weight polymers than corresponding catalyst with conventional silica support.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Topics in Catalysis
ISSN
1022-5528
e-ISSN
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Volume of the periodical
53
Issue of the periodical within the volume
3-4
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
10
Pages from-to
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UT code for WoS article
000275558000009
EID of the result in the Scopus database
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