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Bonding Analysis of the [C2O4](2+) Intermediate Formed in the Reaction of CO22+ with Neutral CO2

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F10%3A10062519" target="_blank" >RIV/00216208:11310/10:10062519 - isvavai.cz</a>

  • Alternative codes found

    RIV/67985858:_____/10:00344001 RIV/61388963:_____/10:00344001

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Bonding Analysis of the [C2O4](2+) Intermediate Formed in the Reaction of CO22+ with Neutral CO2

  • Original language description

    The bonding patterns of the [C2O4](2+) dication formed upon interaction of CO22+ with neutral CO2 are investigated using the analysis of domain-averaged Fermi holes (DAFHs). The DAFH approach provides an explanation for the previously observed "asymmetry" of the energy deposition in the pair of CO2+ monocations formed in the thermal reaction CO22+ + CO2 -} [C2O4](2+) -} 2 CO2+, specifically that the CO2+ monocation formed from the dication dissociates far more readily than the CO2+ monocation formed from the neutral molecule.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory

  • ISSN

    1089-5639

  • e-ISSN

  • Volume of the periodical

    114

  • Issue of the periodical within the volume

    24

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

  • UT code for WoS article

    000278805700015

  • EID of the result in the Scopus database