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Crossed-Beam Scattering Studies of Electron-Transfer Processes between the Dication CO22+ and Neutral CO2: Electronic States of Reactants and Products Involved

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F10%3A10062541" target="_blank" >RIV/00216208:11310/10:10062541 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388955:_____/10:00345108 RIV/61388963:_____/10:00345108

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Crossed-Beam Scattering Studies of Electron-Transfer Processes between the Dication CO22+ and Neutral CO2: Electronic States of Reactants and Products Involved

  • Original language description

    Crossed-beam scattering experiments were carried out at collision energies of 4.51 and 2.71 eV to elucidate the electronic states involved in the nondissociative and dissociative electron-transfer reactions observed following CO22+/CO2 collisions. Specifically, we focus on the observation that, in the dissociative electron-transfer reaction, forming CO+, the majority of the CO+ product ions are formed via electron capture by the CO22+ rather than via ejection of an electron from the neutral CO2 reactionpartner. The main channels resulting in nondissociative electron transfer are reactions of the ground (X-3 Sigma(-)(g)) and excited states of CO22+ to give different combinations of the ground and excited states of the product pair of CO2+ ions in whichthe combination AA appears to be significant.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of physical chemistry a

  • ISSN

    1089-5639

  • e-ISSN

  • Volume of the periodical

    114

  • Issue of the periodical within the volume

    23

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database