Influence of the Ti-O-C Angle on the Oxygen-to-Titanium pi-Donation in [Cp-2*Ti(III)OR] Complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F10%3A10070045" target="_blank" >RIV/00216208:11310/10:10070045 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/10:00351878
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Influence of the Ti-O-C Angle on the Oxygen-to-Titanium pi-Donation in [Cp-2*Ti(III)OR] Complexes
Original language description
The constrained geometry alkoxide [Ti(III)(eta(5)-C5Me5){eta(5)-C5Me4CH2CMe2O-kappa O}] (2) and titanocene alcoholates [Cp*2TiOR] for R = 1-adamantyl (3) and pentafluorophenyl (4) were prepared by reacting acetone and the respective alcohols with the singly tucked-in titanocene [Ti(III)(eta(5)-C5Me5)(eta(5):eta(1)-C5Me4CH2)] (1) in order to add the simplest member to constrained geometry alkoxides 5 and 6 and to extend the series of [Cp*2TiOR] (R = Me (8), 'Bu (7), Ph (9), and H (10)) compounds for oneof the most bulky and the most electron attracting substituent. The titanocene alkoxides with the alkoxy carbon atom tethered to one of the cyclopentadienyl ligands showing the crystallographic Ti-O-C angle close to 133 degrees are a suitable group of compounds to be compared with the [Cp*2TiOR] compounds, where the Ti-O-C angle is about 174 degrees for 3 and 7 and 180 degrees for 4.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
29
Issue of the periodical within the volume
17
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
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UT code for WoS article
000281472500013
EID of the result in the Scopus database
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