Semi-organic salts of aniline with inorganic acids: prospective materials for second harmonic generation

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F11%3A10089831" target="_blank" >RIV/00216208:11310/11:10089831 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/C1CE05170A" target="_blank" >http://dx.doi.org/10.1039/C1CE05170A</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c1ce05170a" target="_blank" >10.1039/c1ce05170a</a>

Result language
angličtina
Original language name
Semi-organic salts of aniline with inorganic acids: prospective materials for second harmonic generation
Original language description
Three novel inorganic salts of aniline with sulfuric and selenic acids were prepared and characterized by X-ray structural analysis. Anilinium(1+) selenate, (C(6)H(5)NH(3)(+))(2)SeO(4)(2-), and anilinium sulfate, (C(6)H(5)NH(3)(+))(2)SO(4)(2-), crystallize in the monoclinic space group C2. The crystal structures are based on hydrogen bonded layers of alternating anilinium cations and inorganic anions. Anilinium( 1+) selenate dihydrate, (C(6)H(5)NH(3)(+))(2)SeO(4)(2-)center dot 2H(2)O, crystallizes in the monoclinic space group C2/c. The crystal structure is formed by a network of alternating anilinium cations, selenate anions and water molecules connected by a system of intermolecular hydrogen bonds. The FTIR and Raman spectra of all the compounds havebeen recorded and discussed as well as their crystal structures. According to the DSC curves and temperature dependence of lattice parameters, anilinium sulfate exhibits phase transitions at 217 and 182 K.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F09%2F0878" target="_blank" >GA203/09/0878: Crystal engineering of hydrogen bonded materials for non-linear optics</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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