Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F11%3A10101066" target="_blank" >RIV/00216208:11310/11:10101066 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jorganchem.2011.08.043" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2011.08.043</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2011.08.043" target="_blank" >10.1016/j.jorganchem.2011.08.043</a>

Result language
angličtina
Original language name
Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands
Original language description
Two polar phosphinoferrocene ligands, 1'-(diphenylphosphino)ferrocene-1-carboxamide (1) and 1'-(diphenylphosphino)ferrocene-1-carbohydrazide (2), were synthesized in good yields from 1'-(diphenylphosphino)ferrocene-1-carboxylic acid (Hdpf) via the reactive benzotriazole derivative, 1-[1'-(diphenylphosphino)ferrocene-1-carbonyl]-1H-1,2,3-benzotriazole (3). The hydrazide was further converted via standard condensation reactions to three phosphinoferrocene heterocycles, viz 2-[1'-(diphenylphosphino)ferrocen-1-yl]-1,3,4-oxadiazole (4), 1-[1'-(diphenylphosphino)ferrocen-1-carbonyl]-3,5-dimethyl-1,2-pyrazole (5), and 1-[1'-(diphenylphosphino)ferrocene-1-carboxamido]-3,5-dimethylpyrrole (6). These compounds have been structurally characterized and studied asligands in palladium(II) complexes.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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