ENANTIOSELECTIVE EPOXIDE RING OPENING CATALYZED BY BIS(TETRAHYDROISOQUINOLINE) N,N'-DIOXIDES

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F11%3A10104902" target="_blank" >RIV/00216208:11310/11:10104902 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/11:00369758
Result on the web
<a href="http://cccc.uochb.cas.cz/76/5/0415/" target="_blank" >http://cccc.uochb.cas.cz/76/5/0415/</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1135/cccc2011024" target="_blank" >10.1135/cccc2011024</a>

Result language
angličtina
Original language name
ENANTIOSELECTIVE EPOXIDE RING OPENING CATALYZED BY BIS(TETRAHYDROISOQUINOLINE) N,N'-DIOXIDES
Original language description
Four bis(tetrahydroisoquinoline) N,N'-dioxides were used as catalysts for the epoxide ring opening with tetrachlorosilane under various conditions. A strong solvent effect on asymmetric induction was observed for each of the used catalysts. The highest achieved asymmetric induction for the opening of meso-stilbene oxide was 69% ee. Regarding the cycloalkene oxides, 56% ee was obtained in the reaction with cyclooctene oxide.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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