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Group 4 metallocene complexes with pendant nitrile groups

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F11%3A10106304" target="_blank" >RIV/00216208:11310/11:10106304 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388955:_____/11:00371368

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.jorganchem.2011.02.032" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2011.02.032</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jorganchem.2011.02.032" target="_blank" >10.1016/j.jorganchem.2011.02.032</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Group 4 metallocene complexes with pendant nitrile groups

  • Original language description

    The preparation of a new functionalized cyclopentadienyl ligand bearing a nitrile pendant substituent, (C(5)H(4)CMe(2)CH(2)CN)(-) is reported. The corresponding lithium salt of this ligand (1) was prepared by the reaction of in situ lithiated acetonitrile with 6,6-dimethylfulvene. The ligand was subsequently utilized for the synthesis of group 4 metal complexes [(eta(5)eC(5)H(4)CMe(2)CH(2)CN)(2)MCl(2)] (M = Ti, 2; M = Zr, 3; M - Hf, 4), [(eta(5)eC(5)H(5)) (eta(5)eC(5)H(4)CMe(2)CH(2)CN)MCl(2)] (M - Ti, 7; M Zr, 8), and [(eta(5)-C(5)Me(5)) (eta(5) C(5)H(4)CMe(2)CH(2)CN)(2)ZrCl(2)] (9). Alternative route to 2 comprised the preparation of half-sandwich complex [(h5eC5H4CMe2CH2CN)TiCl(3)] (6). The prepared compounds were characterized by common spectroscopic methods and the solid state structures of complexes 2, 3, 4, 7, and 9 were determined by the single-crystal X-ray diffraction analysis. In addition, compound 7 was converted to the corresponding dimethyl derivative [(eta(5)eC(5)H(5)) (e

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Organometallic Chemistry

  • ISSN

    0022-328X

  • e-ISSN

  • Volume of the periodical

    696

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    9

  • Pages from-to

    2364-2372

  • UT code for WoS article

    000290022200013

  • EID of the result in the Scopus database