Simulation of the effects of complex- formation equilibria in electrophoresis: II. Experimental verification
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10120348" target="_blank" >RIV/00216208:11310/12:10120348 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/elps.201100503" target="_blank" >http://dx.doi.org/10.1002/elps.201100503</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/elps.201100503" target="_blank" >10.1002/elps.201100503</a>
Alternative languages
Result language
angličtina
Original language name
Simulation of the effects of complex- formation equilibria in electrophoresis: II. Experimental verification
Original language description
The complete mathematical model of electromigration in systems with complexation agents introduced in the Part I of this article (V. Hruska et al., Eletrophoresis, 2012, 33, this issue), which was implemented into our simulation program Simul 5, was verified experimentally. Three different chiral selector (CS) systems differing in the type of the CS, the magnitude of the complexation constants as well as in the experimental conditions were selected for verification. The experiments and simulations wereperformed at various concentrations of the CSs in order to discuss the influence of the concentration of the CS on the separation. The simulated and experimental electropherograms show very good agreement in the position, shape and amplitude of the analyte peaks. The new Simul 5 Complex offers a deep insight into electrophoretical separations that take place in systems containing complexing agents, for example into enantiomer separations. Using Simul 5 Complex we were able to predict and
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F08%2F1428" target="_blank" >GA203/08/1428: Capillary electrophoresis with multidimensinal detection and its application to separation and characterization of biopolymers</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electrophoresis
ISSN
0173-0835
e-ISSN
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Volume of the periodical
33
Issue of the periodical within the volume
6
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
948-957
UT code for WoS article
000303155700009
EID of the result in the Scopus database
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