Chiral HPLC Separation on Derivatized Cyclofructan Versus Cyclodextrin Stationary Phases
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10124189" target="_blank" >RIV/00216208:11310/12:10124189 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/00032719.2012.686128" target="_blank" >http://dx.doi.org/10.1080/00032719.2012.686128</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/00032719.2012.686128" target="_blank" >10.1080/00032719.2012.686128</a>
Alternative languages
Result language
angličtina
Original language name
Chiral HPLC Separation on Derivatized Cyclofructan Versus Cyclodextrin Stationary Phases
Original language description
Cyclodextrins (CDs) and cyclofructans (CFs) are chiral cyclic oligosaccharides. While ?-CD is composed of seven glucopyranose units forming rigid cavity, hydrophobic inside, CF6 and CF7, contain six and seven fructofuranose units, respectively, creatinga polar crown ether core. These basic structures can be easily derivatized to form even more potential chiral selectors that enable enantioselective separation of various chiral compounds. Chiral stationary phases (CSPs) based on CFs and CDs that were derivatized with the same derivatization group, either dimethylphenyl or R-naphthylethyl, were compared. A set of analytes with different interaction possibilities was used for characterization of retention and enantioseparation abilities of these CSPs innormal separation mode of HPLC. The results showed that both cyclic oligosaccharide structure and derivatization group influenced the retention/separation behavior of analytes. Complementary enantioseparations were obtained for some analy
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/LH11018" target="_blank" >LH11018: Cyclofructans and their derivatives as new chiral selectors for liquid chromatography and capillary electrophoresis</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Analytical Letters
ISSN
0003-2719
e-ISSN
—
Volume of the periodical
45
Issue of the periodical within the volume
16
Country of publishing house
US - UNITED STATES
Number of pages
15
Pages from-to
2344-2358
UT code for WoS article
000310613800007
EID of the result in the Scopus database
—