Synthesis, molecular structure and electrochemistry of gold(I) complexes with 1-(diphenylphosphino)-1'-[(diphenylphosphino)methyl]ferrocene
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10126173" target="_blank" >RIV/00216208:11310/12:10126173 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jorganchem.2012.06.007" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2012.06.007</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2012.06.007" target="_blank" >10.1016/j.jorganchem.2012.06.007</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis, molecular structure and electrochemistry of gold(I) complexes with 1-(diphenylphosphino)-1'-[(diphenylphosphino)methyl]ferrocene
Original language description
Depending on the reaction stoichiometry, 1-(diphenylphosphino)-1'-[(diphenylphosphino) methyl]ferrocene (1) reacts with [AuCl(tht)] (tht = tetrahydrothiophene) to afford an insoluble polymer formulated as [AuCl(1)]n (2) or ligand-bridged digold(I) complex, [(mu-1)(AuCl)2] (3). The latter compound readily undergoes metathesis reactions with anionic reagents such as in situ generated acetylides, thiocyanate or N,N-diethyldithiocarbamate to give the corresponding digold(I) complexes [(mu-1)(AuY)2], where Yis CCPh (4), CCFc (5; Fc = ferrocenyl), SCN (6), and Et2NCS2 (7). Similar reaction of 3 with a dithiolate formed from propane-1,3-dithiol and sodium methoxide affords a macrocyclic bis-chelate [(mu-1)(AuSCH2CH2CH2SAu)] (8). Compounds 2-8 have been characterized by spectroscopic methods (multinuclear NMR, ESI, MS, UV-vis and IR) and by elemental analysis, and the molecular structures of 3.1/2C2H4Cl2, 4.2CHCl3, 7.2CHCl3, and 8 have been determined by single-crystal X-ray diffraction analy
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP207%2F10%2F0176" target="_blank" >GAP207/10/0176: Homologous functional phosphinoferrocene ligands for coordination chemistry and catalysis</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
716
Issue of the periodical within the volume
neuveden
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
10
Pages from-to
110-119
UT code for WoS article
000307821700016
EID of the result in the Scopus database
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