Unprecedented Meta-Substitution of Calixarenes: Direct Way to Inherently Chiral Derivatives

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10127587" target="_blank" >RIV/00216208:11310/12:10127587 - isvavai.cz</a>
Alternative codes found
RIV/67985858:_____/12:00380824 RIV/61388963:_____/12:00380824 RIV/60461373:22310/12:43894917 RIV/60461373:22810/12:43894917
Result on the web
<a href="http://dx.doi.org/10.1021/ol301420t" target="_blank" >http://dx.doi.org/10.1021/ol301420t</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ol301420t" target="_blank" >10.1021/ol301420t</a>

Result language
angličtina
Original language name
Unprecedented Meta-Substitution of Calixarenes: Direct Way to Inherently Chiral Derivatives
Original language description
Electrophilic aromatic substitution in the calix[n]arene series is a well-established procedure leading exclusively to para-substituted derivatives. An unprecedented regioselectivity of the mercuration reaction leading to the meta-substituted calix[4]arenes is described. These compounds represent a new type of substitution pattern in classical calixarene chemistry and open the door for the straightforward synthesis of inherently chiral receptors based on calixarenes.
Czech name
—
Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F12%2F2027" target="_blank" >GAP207/12/2027: Synthesis and applications of inherently chiral calixarenes</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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