Formation of argon-boron bonds in the reactions of BFn+/2+ cations with neutral argon

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10128793" target="_blank" >RIV/00216208:11310/12:10128793 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/12:00383798
Result on the web
<a href="http://dx.doi.org/10.1016/j.ijms.2012.05.006" target="_blank" >http://dx.doi.org/10.1016/j.ijms.2012.05.006</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ijms.2012.05.006" target="_blank" >10.1016/j.ijms.2012.05.006</a>

Result language
angličtina
Original language name
Formation of argon-boron bonds in the reactions of BFn+/2+ cations with neutral argon
Original language description
Experimental data on the reactions of argon with BFn+ monocations (n = 0-3) and BFn2+ dications (n = 1, 2) and dications reveal the formation of the new argon species ArBF2+ and ArBF2+. Theoretical calculations on the stability of these ions using density functional theory confirm the formation of the rare-gas compounds, but their formation is only exothermic for the reaction Ar + BF22+ -> ArBF2+ + F. According to theory, the corresponding neon compounds all involve endothermic pathways and could henceonly be formed via involvement of excited states.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F09%2F1223" target="_blank" >GA203/09/1223: Bond-forming reactions of hydrocarbon dications</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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