Reactions of Doubly Ionized Benzene with Nitrogen and Water: A Nitrogen-Mediated Entry into Superacid Chemistry
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10132866" target="_blank" >RIV/00216208:11310/12:10132866 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/12:00379235 RIV/61388963:_____/12:00379235
Result on the web
<a href="http://dx.doi.org/10.1002/cphc.201200313" target="_blank" >http://dx.doi.org/10.1002/cphc.201200313</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cphc.201200313" target="_blank" >10.1002/cphc.201200313</a>
Alternative languages
Result language
angličtina
Original language name
Reactions of Doubly Ionized Benzene with Nitrogen and Water: A Nitrogen-Mediated Entry into Superacid Chemistry
Original language description
Even in the highly diluted gas phase, rather than electron transfer the benzene dication C6H6(2+) undergoes association with dinitrogen to form a transient C6H6N2(2+) dication which is best described as a ring-protonated phenyl diazonium ion. Isotopic labeling studies, photoionization experiments using synchrotron radiation, and quantum chemical computations fully support the formation of protonated diazonium, which is in turn a prototype species of superacidic chemistry in solution. Additionally, reactions of C6H6(2+) with background water involve the transient formation of diprotonated phenol and, among other things, afford a long-lived C6H6OH2(2+) dication, which is attributed to the hydration product of Hogeveens elusive pyramidal structure of C6H6(2+), as the global minimum of doubly ionized benzene. Nitrogen is essential for the formation of the C6H6OH2(2+) dication in that it mediates the formation of the water adduct, while the bimolecular encounter of the C6H6(2+) dication wit
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemphyschem : a European journal of chemical physics and physical chemistry
ISSN
1439-4235
e-ISSN
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Volume of the periodical
13
Issue of the periodical within the volume
11
Country of publishing house
GB - UNITED KINGDOM
Number of pages
11
Pages from-to
2688-2698
UT code for WoS article
000306900700013
EID of the result in the Scopus database
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