Silver(I) and gold(I) complexes of diethylmalonate

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10133128" target="_blank" >RIV/00216208:11310/12:10133128 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ijms.2012.08.019" target="_blank" >http://dx.doi.org/10.1016/j.ijms.2012.08.019</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ijms.2012.08.019" target="_blank" >10.1016/j.ijms.2012.08.019</a>

Result language
angličtina
Original language name
Silver(I) and gold(I) complexes of diethylmalonate
Original language description
Complexes of diethylmalonate, a common building block in organic synthesis, with gold(l) and silver(l) have been investigated. Both metal cations coordinate between the two carbonyl-oxygen atoms of diethylmalonate. The gold(I) complex should also bear diethylmalonate in the enol-form in the gas phase, while the diketo form is preferred in the condensed phase. The IRMPD spectrum shows that the diketo form is retained upon electrospray ionization also in the gaseous diethylmalonate complex with Au(PMe3)(+). The diethylmalonate complex with a bare silver cation undergoes an association with a water molecule in the gas phase. Spectra of the bare complex and the water-tagged complex are compared.
Czech name
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Czech description
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Project
<a href="/en/project/GAP207%2F11%2F0338" target="_blank" >GAP207/11/0338: Reaction mechanisms in organometallic chemistry</a>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP) Z - Vyzkumny zamer (s odkazem do CEZ) I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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