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On the Solubility and Lipophilicity of Metallacarborane Pharmacophores

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F13%3A10134026" target="_blank" >RIV/00216208:11310/13:10134026 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388963:_____/13:00394143 RIV/60461373:22340/13:43895056

  • Result on the web

    <a href="http://dx.doi.org/10.1021/mp300565z" target="_blank" >http://dx.doi.org/10.1021/mp300565z</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/mp300565z" target="_blank" >10.1021/mp300565z</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    On the Solubility and Lipophilicity of Metallacarborane Pharmacophores

  • Original language description

    Metallacarborane moieties have been identified as promising pharmacophores. The pharmaceutical use of such compounds is, however, complicated by their low solubility and tendency to self-assemble in aqueous solution. In this work, we estimated the solubilities of a vast series of metallacarboranes [cobalt bis(dicarbollide) derivatives] in pure water, saline, and saline with human serum albumin as a model of blood plasma. In addition, we determined the octanolMINUS SIGN water partition coefficients (Pow)as a lipophilicity descriptor. Pow weakly correlates with the water solubility of metallacarboranes, whereas the ability of HSA to increase the solubility of metallacarboranes correlates well with their Pow values. Because metallacarboranes are known inhibitors of HIV protease, the possible correlation between Pow and the ability to inhibit HIV protease was investigated. Results from this study indicate that interaction of metallacarborane inhibitors with HIV protease is driven by speci

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Molecular Pharmaceutics

  • ISSN

    1543-8384

  • e-ISSN

  • Volume of the periodical

    10

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    1751-1759

  • UT code for WoS article

    000318669600024

  • EID of the result in the Scopus database