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Growth, electronic absorption and vibrational spectral analysis of semiorganic nonlinear optical material potassium acid phthalate: A scaled quantum mechanical force field study

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F13%3A10139614" target="_blank" >RIV/00216208:11310/13:10139614 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.molstruc.2013.02.033" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2013.02.033</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.molstruc.2013.02.033" target="_blank" >10.1016/j.molstruc.2013.02.033</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Growth, electronic absorption and vibrational spectral analysis of semiorganic nonlinear optical material potassium acid phthalate: A scaled quantum mechanical force field study

  • Original language description

    The spectroscopic properties of the crystallized semiorganic nonlinear optical molecule Potassium Acid Phthalate (RAP) have been recorded and analyzed by FT-IR, Raman and UV techniques. The spectra were interpreted with the aid of normal coordinate analysis following structure optimizations and force field calculations based on density functional theory (DFT) at the B3LYP/6-311+G(d,p) level of theory. Normal coordinate calculations were performed using the DFT force field corrected by a recommended setof scaling factors yielding fairly good agreement between the observed and calculated wavenumbers. RAP is thermally stable up to 275.0 degrees C and optically transparent in the visible region.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Molecular Structure

  • ISSN

    0022-2860

  • e-ISSN

  • Volume of the periodical

    1040

  • Issue of the periodical within the volume

    květen

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    9

  • Pages from-to

    155-163

  • UT code for WoS article

    000318961000021

  • EID of the result in the Scopus database