Structural and electrochemical studies of Sm@D3h-C74 reveal a weak metal-cage interaction and a small band gap species

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F13%3A10159065" target="_blank" >RIV/00216208:11310/13:10159065 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c3nr03447j" target="_blank" >http://dx.doi.org/10.1039/c3nr03447j</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c3nr03447j" target="_blank" >10.1039/c3nr03447j</a>

Result language
angličtina
Original language name
Structural and electrochemical studies of Sm@D3h-C74 reveal a weak metal-cage interaction and a small band gap species
Original language description
A metallofullerene Sm@D3h-C74 that contains a divalent rare-earth metal has been studied structurally and electrochemically. The crystallographic analysis revealed that the endohedral Sm atom is more or less motional rather than being localized at a sitewhere the pyracylene motif is nearby. This suggests a weaker metal-pyracylene interaction in Sm@D3h-C74 relative to that in MII@C74 (M 1/4 Group II metal), thus confirming the importance of the metal variety. The electrochemical studies showed a major difference between the redox properties of Sm@D3h-C74 and other Sm-fullerenes and indicated a small band gap for the title compound.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP208%2F10%2F0179" target="_blank" >GAP208/10/0179: Computational studies of nanomaterials based on fullerenes</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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