Synthesis and structural characterisation of Pd(II) and Pt(II) complexes with a flexible, ferrocene-based P,S-donor amidophosphine ligand

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10192466" target="_blank" >RIV/00216208:11310/14:10192466 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1039/c3dt52760c" target="_blank" >http://dx.doi.org/10.1039/c3dt52760c</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c3dt52760c" target="_blank" >10.1039/c3dt52760c</a>

Result language

angličtina

Original language name

Synthesis and structural characterisation of Pd(II) and Pt(II) complexes with a flexible, ferrocene-based P,S-donor amidophosphine ligand

Original language description

1'-Diphenylphosphino-1-{[(2-(methylthio)ethyl)amino]carbonyl}ferrocene (1), accessible via amidation of 1'-(diphenylphosphino)ferrocene-1-carboxylic acid (Hdpf) with 2-(methylthio)ethylamine, reacts with [PdCl2(cod)] (cod = cycloocta-1,5-diene) at a 1:1metal-to-ligand ratio to give trans-[PdCl2(1-kappa P-2,S)] (trans-2) as the sole product. A similar reaction with [PtCl2(cod)]affords a mixture of cis- and trans[PtCl2(1-kappa P-2,S)] (cis- and trans-3), which can be separated by fractional crystallisation. Complexation reactions performed with 2 equiv. of the ligand are less selective, yielding mixtures of the expected bis-phosphine complexes (i.e., trans-[PdCl2(1-kappa P)(2)], or a mixture of cis- and trans-[PtCl2(1-kappa P)(2)]) with the respective monophosphine complexes. The structures of 1, trans-2, cis-3 and trans-3 determined by X-ray diffraction demonstrate the ability of the title ligand to act as a flexible cis- or trans-P,S-chelate donor (the ligand bite angles are 174.03(2)

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA13-08890S" target="_blank" >GA13-08890S: Polar ferrocene amidophosphine ligands for catalytic applications</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2014

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Dalton Transactions

ISSN

1477-9226

e-ISSN

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Volume of the periodical

43

Issue of the periodical within the volume

4

Country of publishing house

IN - INDIA

Number of pages

10

Pages from-to

1599-1608

UT code for WoS article

000328885300016

EID of the result in the Scopus database

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