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Hydrothermally grown porous FeVO4 nanorods and their integration as active material in gas-sensing devices

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10194154" target="_blank" >RIV/00216208:11310/14:10194154 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1039/c3ta12821k" target="_blank" >http://dx.doi.org/10.1039/c3ta12821k</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c3ta12821k" target="_blank" >10.1039/c3ta12821k</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Hydrothermally grown porous FeVO4 nanorods and their integration as active material in gas-sensing devices

  • Original language description

    Controllable fabrication of highly porous iron vanadate (FeVO4) thick film consisting of disordered nanorods suitable for gas penetration and permeation was achieved by hydrothermal synthesis of fervanite-like FeVO4 center dot 1.1H2O. The subsequent dehydration to FeVO4 was investigated by Fe-57 Mossbauer spectroscopy (DQS), DTA, magnetic susceptibility (c) and electron microscopy (REM/TEM). Their integration in gas sensing devices as porous layer via polymer-blended (PVDF) doctor-blading approach was successfully demonstrated followed by investigations of their electric properties and oxygen sensing capability. The probed I-U behaviour and UV-Vis measurements confirmed the semiconducting nature of triclinic FeVO4 (E-g = 2.72 eV) and exhibited an activation energy for electric conduction of 0.46 eV. The best sensitivity of 0.29 +/- 0.01 (m = -3.4 +/- 0.1) could be obtained at an optimal working temperature of 250 degrees C.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Materials Chemistry A

  • ISSN

    2050-7488

  • e-ISSN

  • Volume of the periodical

    2

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    7

  • Pages from-to

    1862-1868

  • UT code for WoS article

    000329935700035

  • EID of the result in the Scopus database