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Enantioselective methodologies using N-carbamoyl-imines

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10195546" target="_blank" >RIV/00216208:11310/14:10195546 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1039/c3cs60321k" target="_blank" >http://dx.doi.org/10.1039/c3cs60321k</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c3cs60321k" target="_blank" >10.1039/c3cs60321k</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Enantioselective methodologies using N-carbamoyl-imines

  • Original language description

    Nucleophilic addition to carbon-nitrogen double bonds (imines) represents one of the most common strategies for the synthesis of amine derivatives. In order to circumvent the problem associated with low reactivity of imines in nucleophilic addition, various imines with electron-withdrawing groups at nitrogen have been studied, and many of them were successfully applied in asymmetric methodologies. Especially N-carbamoyl imines were found to be useful in the enantioselective synthesis of various organiccompounds, due to their increased reactivity toward nucleophiles as well as limited difficulties connected with the removal of the carbamoyl moiety in target molecules. The aim of this review is to cover enantioselective methods based on N-carbamoyl imines, focusing on synthetically useful protocols.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP207%2F10%2F0428" target="_blank" >GAP207/10/0428: Enantioselective organocatalytic alpha-alkynylation,alkenylation and arylation of aldehydes and ketones</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemical Society Reviews

  • ISSN

    0306-0012

  • e-ISSN

  • Volume of the periodical

    43

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    20

  • Pages from-to

    611-630

  • UT code for WoS article

    000329071400009

  • EID of the result in the Scopus database