Morphologically Tunable Coassembly of Double Hydrophilic Block Polyelectrolyte with Oppositely Charged Fluorosurfactant
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10284311" target="_blank" >RIV/00216208:11310/14:10284311 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11110/14:10284311
Result on the web
<a href="http://dx.doi.org/10.1021/ma500622a" target="_blank" >http://dx.doi.org/10.1021/ma500622a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ma500622a" target="_blank" >10.1021/ma500622a</a>
Alternative languages
Result language
angličtina
Original language name
Morphologically Tunable Coassembly of Double Hydrophilic Block Polyelectrolyte with Oppositely Charged Fluorosurfactant
Original language description
We report on the formation and structure development of polyelectrolytesurfactant complexes, PES, of double hydrophilic block copolymers poly(sodium 2-sulfamate-3-carboxylate isoprene)-block-poly(ethylene oxide), PSCIPEO, and cationic fluorosurfactant, N-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)pyridinium chloride, HFDPCl. We compare the behavior of four PSCIPEO samples differing in comonomer composition and polyisoprene block modification degree. Coassembled coreshell nanoparticles with the core formed by the PSCI/HFDPCl complex and the shell of PEO blocks were characterized by microscopic techniques (cryogenic transmission electron microscopy, atomic force microscopy) and by small-angle neutron scattering. Interactions between PSCIPEO and HFDPCl were studied by isothermal titration calorimetry. We show that the bulky fluorosurfactant ions drive the coassembly toward structures with less curved interfaces such as cylindrical and wormlike micelles or vesicles. We also
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Macromolecules
ISSN
0024-9297
e-ISSN
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Volume of the periodical
47
Issue of the periodical within the volume
20
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
7081-7090
UT code for WoS article
000343949500010
EID of the result in the Scopus database
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