Separation of planar rotamers through intramolecular hydrogen bonding in polysubstituted 5-nitrosopyrimidines

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10287334" target="_blank" >RIV/00216208:11310/14:10287334 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/14:00435160 RIV/60461373:22330/14:43897375
Result on the web
<a href="http://dx.doi.org/10.1039/c4cc06978a" target="_blank" >http://dx.doi.org/10.1039/c4cc06978a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c4cc06978a" target="_blank" >10.1039/c4cc06978a</a>

Result language
angličtina
Original language name
Separation of planar rotamers through intramolecular hydrogen bonding in polysubstituted 5-nitrosopyrimidines
Original language description
While purifying new polysubstituted 5-nitrosopyrimidines, the unique separation of pairs of rotamers as chemical species, stabilized by a single intramolecular hydrogen bond and differing only in nitroso group orientation, was achieved. This interestingstereochemical phenomenon is compared to the well-known atropisomerism.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Result description