Electrochemical Reduction of 1,3-Alt-tetranitrothiacalix[4]arenes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10319227" target="_blank" >RIV/00216208:11310/14:10319227 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/14:00437198
Result on the web
<a href="http://www.bestservis.eu/upload/file/Sbornik_metody14.pdf" target="_blank" >http://www.bestservis.eu/upload/file/Sbornik_metody14.pdf</a>
DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Electrochemical Reduction of 1,3-Alt-tetranitrothiacalix[4]arenes
Original language description
Calixarenes are organic molecules which contain several aromatic units (in this work four) connected by methylene (""calixarenes"") or sulfur (""thiacalixarenes"") bridges. Calix[4]arenes can exist in four defined conformations: cone-, partial cone-, 1,2- and 1,3-alternating (Fig. 1). The conformational stability of a (thia)calix[4]arene is controlled by the size of the substituents on the upper or the lower rim, or by other interactions (e.g. hydrogen bonds). These compounds are very attractive for supramolecular chemists, since they have the shape of a cavity, being able to exhibit host-guest interaction according to the substitution 1,2. The calixarene skeleton itself is not reducible. Therefore it's necessary to introduce a suitable redox probe in the calixarene frame in order to use electrochemical methods for investigations of calixarene properties. For the purpose of this study the nitro group was chosen because its electrochemical reduction proceeds easily in a well-defined way.
Czech name
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Czech description
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection
Sborník přednášek mezinárodní odborné konference XXXIV. Moderní Elektrochemické Metody Jetřichovice 19.- 23. května 2014
ISBN
978-80-905221-2-1
ISSN
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e-ISSN
neuvedeno
Number of pages
5
Pages from-to
85-89
Publisher name
Srsenová Lenka - Best servis Ústí nad Labem
Place of publication
Ústí nad Labem
Event location
Jetrichovice
Event date
May 19, 2014
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000353446900018

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