Synthesis of phosphinoferrocene amides and thioamides from carbamoyl chlorides and the structural chemistry of Group 11 metal complexes with these mixed-donor ligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10292899" target="_blank" >RIV/00216208:11310/15:10292899 - isvavai.cz</a>
Result on the web
<a href="http://pubs.rsc.org/en/content/articlepdf/2015/dt/c4dt03279a" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2015/dt/c4dt03279a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c4dt03279a" target="_blank" >10.1039/c4dt03279a</a>

Result language
angličtina
Original language name
Synthesis of phosphinoferrocene amides and thioamides from carbamoyl chlorides and the structural chemistry of Group 11 metal complexes with these mixed-donor ligands
Original language description
The reaction of in situ generated 1'-(diphenylphosphino)-1-lithioferrocene with carbamoyl chlorides, ClC-(E) NMe2, affords the corresponding (thio) amides, Ph(2)PfcC(E) NMe2 (E = O (2), S (3); fc = ferrocene-1,1'-diyl). These compounds as well as their analogues, Ph(2)PfcC(O) NHMe (4) and Ph(2)PfcC(O) NH2 (5), prepared from 1'-(diphenylphosphino) ferrocene-1-carboxylic acid (Hdpf) were studied as ligands for the Group 11 metal ions. In the reactions with [Cu(MeCN)(4)][BF4], the amides give rise to bis-chelate complexes of the type [Cu(L-kappa O-2, P)(2)][BF4]. Similar products, [Ag(L-kappa O-2, P)(2)] ClO4, are obtained from silver(I) perchlorate and 2, 4 or 5. In contrast, the reaction of AgClO4 with 3 produces a unique molecular dimer [Ag(3)-(ClO4-kappa O)](2), where the metal centres are bridged by the sulfur atoms of the P, S-chelating thioamides. The reactions of 2-5 with [AuCl(tht)] (tht = tetrahydrothiophene) afford the expected gold(I)-phosphine complexes, [AuCl(L-kappa P)], co
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA13-08890S" target="_blank" >GA13-08890S: Polar ferrocene amidophosphine ligands for catalytic applications</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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