Popular C82 Fullerene Cage Encapsulating a Divalent Metal Ion Sm2 : Structure and Electrochemistry

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10292901" target="_blank" >RIV/00216208:11310/15:10292901 - isvavai.cz</a>
Result on the web
<a href="http://pubs.acs.org/doi/pdf/10.1021/ic5021884" target="_blank" >http://pubs.acs.org/doi/pdf/10.1021/ic5021884</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ic5021884" target="_blank" >10.1021/ic5021884</a>

Result language
angličtina
Original language name
Popular C82 Fullerene Cage Encapsulating a Divalent Metal Ion Sm2 : Structure and Electrochemistry
Original language description
Two Sm@C82 isomers have been well characterized for the first time by means of 13C NMR spectroscopy, and their structures were unambiguously determined as Sm@C2v(9)- C82 and Sm@C3v(7)-C82, respectively. A combined study of single crystal X-ray diffraction and theoretical calculations suggest that in Sm@C2v(9)-C82 the preferred Sm2+ ion position shall be located in a region slightly off the C2 axis of C2v(9)-C82. Moreover, the electrochemical surveys on these Sm@C82 isomers reveal that their redox activities are mainly determined by the properties of their carbon cages.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP208%2F10%2F1724" target="_blank" >GAP208/10/1724: Molecular simulation studies of structure and dynamics of ice surfaces in the presence of impurities and atmospheric pollutants</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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