Preparation of quaternary pyridinium salts as possible proton conductors
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10293598" target="_blank" >RIV/00216208:11310/15:10293598 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/15:00441379
Result on the web
<a href="http://www.degruyter.com//view/j/chempap.2015.69.issue-3/chempap-2015-0037/chempap-2015-0037.xml" target="_blank" >http://www.degruyter.com//view/j/chempap.2015.69.issue-3/chempap-2015-0037/chempap-2015-0037.xml</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1515/chempap-2015-0037" target="_blank" >10.1515/chempap-2015-0037</a>
Alternative languages
Result language
angličtina
Original language name
Preparation of quaternary pyridinium salts as possible proton conductors
Original language description
On basis of earlier experimental experience, the transfer of protons in salts of the organic cation-inorganic anion type occurs primarily through directional arrangement of the anion-anion type short hydrogen bonds. The submitted work presents the preparation of quaternary pyridinium salts of inorganic hydrogen anions in the absence of solvent molecules in their crystal structure. These substances can form only the above-described anion-anion type hydrogen bonds; in addition, the absence of solvate anions increases the stability of the prepared compounds. A total of six substituted pyridinium salts were prepared, four of which have not been described yet: 1,2,4,6-tetraphenylpyridinium perchlorate, 1-benzyl-2,4,6-trimethylpyridinium perchlorate, 1,4-dimethylpyridinium hydrogen sulphate, 1,4-dimethylpyridinium dihydrogen phosphate, 1,4-dimethylpyridinium hydrogen sulphate, and 1,2-dimethyl-5-ethylpyridinium dihydrogen phosphate. Three of these substances were characterised by X-ray struc
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Papers
ISSN
0366-6352
e-ISSN
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Volume of the periodical
69
Issue of the periodical within the volume
3
Country of publishing house
SK - SLOVAKIA
Number of pages
8
Pages from-to
448-455
UT code for WoS article
000350134900009
EID of the result in the Scopus database
2-s2.0-84921939970