Ce(III) and Lu(III) metal-organic frameworks with Lewis acid metal sites: Preparation, sorption properties and catalytic activity in Knoevenagel condensation

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10293602" target="_blank" >RIV/00216208:11310/15:10293602 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/15:00446854
Result on the web
<a href="http://dx.doi.org/10.1016/j.cattod.2014.07.028" target="_blank" >http://dx.doi.org/10.1016/j.cattod.2014.07.028</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.cattod.2014.07.028" target="_blank" >10.1016/j.cattod.2014.07.028</a>

Result language
angličtina
Original language name
Ce(III) and Lu(III) metal-organic frameworks with Lewis acid metal sites: Preparation, sorption properties and catalytic activity in Knoevenagel condensation
Original language description
Two novel coordination polymers with composition {[Ln(BTC)(H2O)]center dot DMF}(n) (where Ln = Ce(III) (1) and Lu(III) (2), BTC = benzene-1,3,5-tricarboxylate, DMF =N,N'-dimethylformamide) have been prepared under solvothermal conditions. Properties of the compounds were investigated by single crystal X-ray diffraction, high-energy powder X-ray diffraction during in-situ heating, thermogravimetry with simultaneous evolved gas analysis, infrared spectroscopy performed at different temperatures, elementalanalysis and inductively coupled plasma mass spectrometry. Sorption properties of the synthesized complexes were investigated using nitrogen and carbon dioxide adsorption experiments. Catalytic activity of compound 2 was tested in Knoevenagel condensation reactions in a series of aromatic and non-aromatic aldehydes with different active methylene compounds (malononitrile, methyl cyanoacetate), in which the reactivity of aldehydes in condensation reactions increases in the order: 2-napht
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GA14-07101S" target="_blank" >GA14-07101S: Combined Experimental and Theoretical Investigation of Catalytic Properties of Metal Organic Frameworks</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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