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Time-Resolved Transient Optical Absorption Study of Bis(terpyridyl)oligothiophenes and Their Metallo-Supramolecular Polymers with Zn(II) Ion Couplers

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10294860" target="_blank" >RIV/00216208:11310/15:10294860 - isvavai.cz</a>

  • Alternative codes found

    RIV/61389013:_____/15:00445857

  • Result on the web

    <a href="http://pubs.acs.org/doi/abs/10.1021/jp512213s" target="_blank" >http://pubs.acs.org/doi/abs/10.1021/jp512213s</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/jp512213s" target="_blank" >10.1021/jp512213s</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Time-Resolved Transient Optical Absorption Study of Bis(terpyridyl)oligothiophenes and Their Metallo-Supramolecular Polymers with Zn(II) Ion Couplers

  • Original language description

    alpha,omega-Bis(terpyridyl)oligothiophenes spontaneously assemble with Zn(II) ions giving conjugated constitutional dynamic polymers (dynamers) of the metallo-supramolecular class, which potentially might be utilized in optoelectronics. Their photophysical properties, which are of great importance in this field of application, are strongly influenced by the dynamic morphology. It was assessed in this study by using ultrafast pump probe optical absorption spectroscopy. We identified and characterized relaxation processes running in photoexcited molecules of these oligomers and dynamers and show impacts of disturbed coplanarity of adjacent rings (twisting the thiophene thiophene and thiophene terpyridyl bonds by attached hexyl side groups) and Zn(II) ioncouplers on these processes. Major effects are seen in the time constants of rotational relaxation, intersystem crossing, and de-excitation lifetimes. The photoexcited states formed on different repeating units within the same dynarner c

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP108%2F12%2F1143" target="_blank" >GAP108/12/1143: Polyelectrolytic conjugated dynamers: preparation, constitutional dynamics and functional properties of new materials</a><br>

  • Continuities

    S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Physical Chemistry A

  • ISSN

    1089-5639

  • e-ISSN

  • Volume of the periodical

    119

  • Issue of the periodical within the volume

    24

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    12

  • Pages from-to

    6203-6214

  • UT code for WoS article

    000356753600007

  • EID of the result in the Scopus database

    2-s2.0-84935024578