Infrared spectroscopy of CHCl2+ molecular dications

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10295985" target="_blank" >RIV/00216208:11310/15:10295985 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ijms.2014.07.001" target="_blank" >http://dx.doi.org/10.1016/j.ijms.2014.07.001</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ijms.2014.07.001" target="_blank" >10.1016/j.ijms.2014.07.001</a>

Result language
angličtina
Original language name
Infrared spectroscopy of CHCl2+ molecular dications
Original language description
Different isomers of the CHCl2+ dications were studied using infrared predissociation spectroscopy with helium and neon tagging in a low-temperature trapping experiment. It is shown that H-C-Cl2+ isomers form the dominant portion of the trapped dicationsthat were detected by IRPD spectroscopy. Other possible isomers, such as H-Cl-C2+, are depleted by a proton transfer reaction with the helium buffer gas but by using neon tagging it was possible to stabilize the neon complexes of H-Cl-C2+ and detect them in the IRPD experiment. (C) 2014 Elsevier B.V. All rights reserved.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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