Product of dissolution of V2O5 in the choline chloride-urea deep eutectic solvent

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10312778" target="_blank" >RIV/00216208:11310/15:10312778 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/15:33157721
Result on the web
<a href="http://dx.doi.org/10.1016/j.inoche.2015.07.030" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2015.07.030</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.inoche.2015.07.030" target="_blank" >10.1016/j.inoche.2015.07.030</a>

Result language
angličtina
Original language name
Product of dissolution of V2O5 in the choline chloride-urea deep eutectic solvent
Original language description
The previously reported high solubility data for V2O5 in the deep eutectic solvent of choline chloride and urea (ChCl-urea) is the result of forming [H2V10O28](4-) complex anion. Storing this as-prepared solution for about three months at 20 degrees C, anew compound, [(CH3)(3)N(CH2)(2)OH](4) [H2V10O28]center dot 2(NH2)(2)CO (1), was obtained. The solid-state structure is assembled of dihydrogen-decavanadate(V) anions, choline cations and molecules of urea. The crystal structure is further stabilized byelectrostatic interactions and by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds. The V-51 NMR spectroscopy detected the decavanadate anion in the as-prepared solution.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
<a href="/en/project/LO1305" target="_blank" >LO1305: Development of the center of advanced technologies and materials</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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