Synthesis and Catalytic Use of Gold(I) Complexes Containing a Hemilabile Phosphanylferrocene Nitrile Donor

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10313140" target="_blank" >RIV/00216208:11310/15:10313140 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/chem.201502968" target="_blank" >http://dx.doi.org/10.1002/chem.201502968</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.201502968" target="_blank" >10.1002/chem.201502968</a>

Result language
angličtina
Original language name
Synthesis and Catalytic Use of Gold(I) Complexes Containing a Hemilabile Phosphanylferrocene Nitrile Donor
Original language description
Removal of the chloride ligand from [AuCl(1-P)] (2) containing a P-monodentate 1-(diphenylphosphanyl)-1-cyanoferrocene ligand (1), by using silver(I) salts affords cationic complexes of the type [Au(1)]X, which exist either as cyclic dimers [Au(1)](2)X-2(3a, X=SbF6; 3c, X=NTf2) or linear coordination polymers [Au(1)](n)X-n (3a, X=SbF6; 3b, X=ClO4), depending on anion X and the isolation procedure. As demonstrated for 3a, the polymers can be readily cleaved by the addition of donors, such as Cl-, tetrahydrothiophene (tht) or 1, giving rise to the parent compound 2, [Au(tht)(1-P)][SbF6] (5a) or [Au(1-P)(2)][SbF6] (4a), respectively, of which the last two compounds can also be prepared by stepwise replacement of tht in [Au(1-P)(2)][SbF6]. The particularcombination of a firmly coordinated (phosphane) and a dissociable (nitrile) donor moieties renders complexes 3/3 attractive for catalysis because they can serve as shelf-stable precursors of coordinatively unsaturated Au-I fragments, anal
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA13-08890S" target="_blank" >GA13-08890S: Polar ferrocene amidophosphine ligands for catalytic applications</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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